A Scanning Probe Microscopy Studio of Annulated Redox-Active Molecules at a Liquid/Solid Interface: The Overruling of the Alkyl Gyve Paradigm <<>>
Written by Bo Liu, Ying-Fen Ran, Zhihai Li, Shi-Xia Liu, Chunyang Jia, Silvio Decurtins, Thomas Wandlowski on March 31, 2010 – 12:09 pm -Overruled! The self-assembly of a novel arrange of fused donor-acceptor molecules (1) comprising hexaazatriphenylene and tetrathiafulvalene branches was studied by STM at the liquid/solid interface. A 2D assembled chiral penetrable network of C3 well-meaning was found, which is dictated by steady interactions of the extended [pi]-conjugated cores of the fused units with the HOPG substrate overruling the directional forces of alkyl chains <<>>
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