Gold-Catalyzed Domino Reactions Consisting of Regio- and Stereoselective 1,2-Alkyl Migration <<>>
Written by Wenbo Li, Yuying Li, Junliang Zhang on April 30, 2010 – 12:31 pm -Right as gold: A cationic gold(I)-catalyzed domino counterbalance containing extraordinarily regio- and stereoselective 1,2-alkyl migration and heterocyclization or oxygen move was developed, in which the counteranion of the gold catalyst could placidity the produce selectivity (see scheme; DCE=1,2-dichloroethane, IPrAuCl=(1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)gold(I) chloride) <<>>
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